Structure Isomerism : Important Points

Structure Isomerism : Important Points

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IsomersCharacteristicsConditions
Chain IsomersThey have different size of main chain or side chainThey have same nature of locants
Positional IsomersThey have different position of locantsThey should have same size of main chain and side chain and same nature of locant
Functional IsomersDifferent nature of locantChain and positional isomerism is not considered
MetamerismDifferent nature of alkyl group
along a polyvalent functional
group
They should have same nature of functional groups chain & positional isomer is ignored
TautomerismDifferent position of hydrogen
atoms
The two functional isomers remains in dynamic equilibrium to each other

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